The spark decomposition of
and 50%
mixtures (100 kPa) in the presence of a solid insulator struck by an electric arc is studied. The sparks were generated in a cylindrical Monel 400 cell
between a stainless steel point and a stainless steel plane (gap space 0.9 mm) either under a 50 Hz ac voltage (90 J per disconnection) or by discharging a capacitor (3.59 J per spark). The gaseous by-products
,
,
,
,
,
,
and
were assayed by gas chromatography and their yields studied by varying the nature of the insulator material (Megelit, Kel-F (polytrifluorochloroethylene), Teflon, polypropylene, polyethylene, nylon) and the concentration of two additives:
(0 and 0.2%) and
(0 and 0.2%).
As it becomes vaporized under the effect of the discharges, the insulator produces species that can trap the fluorine atoms released from
decomposition and enhance the formation of
by-products. This explains the main results of this work which can be summarized as follows.
(i) Enhancement, by an order of magnitude or more, of
by the insulators.
(ii) A quantity of
formed in the presence of the insulator proportional to the enhancement of
. The ratio between the levels of these compounds proved to be the same regardless of the initial concentration of
or
added to the
and the intensity of the sparks.
(iii) Enhancement of the quantities of
(up to fivefold),
,
and
formed in the presence of an insulator whatever the gas sample studied.
In the presence of an insulator, the
-
mixture led to results rather similar to those of
concerning the levels of
decomposition products formed. In all cases however, i.e. in the presence or absence of insulator or added
or
, the mixture led to decreased formation of the main products:
and
.
Interference was seen to occur between the action of the insulator and that of
and
; this is ascribed to reactions taking place between these molecules or their dissociation fragments.