The recently discovered anomalous photovoltaic effect in ferroelectrics is attracting considerable attention
of specialists in ferroelectricity and solid-state physics. The anomalous nature of the effect is manifested
by the fact that the photo-emf developed in ferroelectrics and pyroelectrics is many orders of magnitude
greater than the band gap and can reach 103–105V. The anomalous photovoltaic effect in ferroelectrics
has found extensive applications in volume phase holography. A review is given of the experimental
investigations of the anomalous photovoltaic effect in ferroelectrics and also of the models proposed to
explain this effect.