A systematic theory of sudden perturbations is derived for quantum systems whose states are described
both by wave functions (a pure ensemble) and by a quantum density operator (a mixed ensemble). A
perturbation series is written in powers of the parameter ωτ, which is small when the perturbation is
"sudden"; ℏω is the typical eigenvalue of the unperturbed system; and τ is the characteristic collision
time. When the perturbation
(t), taken at different times, commutes with itself, the theory yields a
compact analytic expression for the probabilities for stimulated transitions for any value of Vτ /ℏ. The
results of many cross-section calculations for atomic collision processes are discussed from a common
standpoint: the processes are treated as "jarring" processes which stimulate transitions in the quantum
system. If a momentum δp is rapidly transferred to the system in a collision, regardless of the physical
nature of the "jarring," the probabilities for the stimulated transitions are governed by the parameter
N ∼δp·δR/ℏ where δR is a measure of the uncertainty in the coordinates which is due to the
relatively slow motions in the unperturbed system.