An investigation was made of pulsed stimulated emission due to vibrational
transitions in the ground electronic state of CO excited by discharges in pure CO and
in mixtures of CO with helium, argon, and xenon. It was found that the output
power, shape and duration of the output pulses, and spectral composition of the
stimulated radiation were different when discharges took place in pure CO from the
corresponding parameters obtained for mixtures. Moreover, the discharge conditions
had a strong influence on all these parameters. The experimental results indicated that
different mechanisms of the population inversion of the active levels took place in the
investigated mixtures. Allowance for the excitation and deexcitation of the vibrational
levels by electrons, collisional exchange of the vibrational quanta (ν-ν exchange), and
excitation via higher electronic states of the molecules explained the experimental
observations.