We examine in the context of general relativity the dynamics of a spatially flat Robertson–Walker universe filled with a classical minimally coupled scalar field ϕ of exponential potential V(ϕ) ∼ exp(−μϕ) plus pressureless baryonic matter. This system is reduced to a first-order ordinary differential equation for Ωϕ(wϕ) or q(wϕ), providing direct evidence on the acceleration/deceleration properties of the system. As a consequence, for positive potentials, passage into acceleration not at late times is generically a feature of the system for any value of μ, even when the late-times attractors are decelerating. Furthermore, the structure formation bound, together with the constraints Ωm0 ≈ 0.25 − 0.3, −1 ⩽ wϕ0 ⩽ −0.6, provides, independently of initial conditions and other parameters, the necessary condition , while the less conservative constraint −1 ⩽ wϕ ⩽ −0.93 gives . Special solutions are found to possess intervals of acceleration. For the almost cosmological constant case wϕ ≈ −1, the general relation Ωϕ(wϕ) is obtained. The generic (nonlinearized) late-times solution of the system in the plane (wϕ, Ωϕ) or (wϕ, q) is also derived.