Two-photon ionization of Na2 has been performed in the presence of a d.c. electric field F. Using the A1Σu+ (υ' = 0, J') state as an intermediate level, it is possible to excite only the (υ+ = 0, N+ ≃ J' ± 1) states of the ion. At low J' values, the field F is found to shift the ionization threshold following a - √F law. At higher J' values, this is not the case, and our results show that the electric field induces rotational autoionization, so that the threshold corresponds to a level N+ ≪ J'.