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Nonlinear rheology of a highly supercooled liquid

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1997 EDP Sciences
, , Citation R. Yamamoto and A. Onuki 1997 EPL 40 61 DOI 10.1209/epl/i1997-00419-1

0295-5075/40/1/61

Abstract

We numerically examine nonlinear rheology of a highly supercooled two-di men sional fluid in shear flow via molecular-dynamics simulation. The viscosity exhibits marked shear-thinning behavior when the shear rate dot gamma exceeds the inverse of the α relaxation time τα. Bond breakage events among particle pairs are found to occur collectively in clusters. The characteristic size ξ of such clusters grows strongly with lowering the temperature and decreases rapidly with increasing dot gamma as ξ ∼ τb(dot gamma)1/4. Here 1/τb(dot gamma) is the bond breakage rate tending to 1/τα for dot gammaτα ≪ 1 and growing as dot gamma for dot gammaτα ≫ 1. The viscosity is of order τb(dot gamma) in glassy states.

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10.1209/epl/i1997-00419-1