Abstract
We numerically examine nonlinear rheology of a highly supercooled two-di men sional fluid in shear flow via molecular-dynamics simulation. The viscosity exhibits marked shear-thinning behavior when the shear rate exceeds the inverse of the α relaxation time τα. Bond breakage events among particle pairs are found to occur collectively in clusters. The characteristic size ξ of such clusters grows strongly with lowering the temperature and decreases rapidly with increasing as ξ ∼ τb()1/4. Here 1/τb() is the bond breakage rate tending to 1/τα for τα ≪ 1 and growing as for τα ≫ 1. The viscosity is of order τb() in glassy states.
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