Fast relaxation in amorphous polymers: Relation to free volume

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1997 EDP Sciences
, , Citation V. N. Novikov et al 1997 EPL 40 165 DOI 10.1209/epl/i1997-00440-4

0295-5075/40/2/165

Abstract

A model of the fast relaxation process in amorphous polymers is presented based on the damping of the boson peak vibrations by the free-volume fluctuations. Comparison of the fast relaxation in polycarbonate as is seen in the low-frequency Raman spectra with the positron annihilation lifetime spectroscopy data for the fractional free volume in a broad temperature interval 50–450 K shows an apparent correlation between the relaxation strength and the free volume, in good agreement with the predictions of the model.

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10.1209/epl/i1997-00440-4