Kinetic regimes and cross-over times in many-particle reacting systems

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1999 EDP Sciences
, , Citation B. O'Shaughnessy and D. Vavylonis 1999 EPL 45 653 DOI 10.1209/epl/i1999-00217-9

0295-5075/45/6/653

Abstract

We study kinetics of single-species reactions ("A + A → ∅") for general local reactivity Q and dynamical exponent z (rms displacement xtt1/z.) For small molecules z = 2, whilst z = 4,8 for certain polymer systems. For dimensions d above the critical value dc = z, kinetics are always mean field (MF). Below dc, the density nt initially follows MF decay, n0ntn02Qt. A 2-body diffusion-controlled regime follows for strongly reactive systems (Q > Q* ∼ n0(zd)/d) with n0ntn02xtd. For Q < Q*, MF kinetics persist, with nt ∼ 1/Qt. In all cases nt ≈ 1/xtd at the longest times. Our analysis avoids decoupling approximations by instead postulating weak physically motivated bounds on correlation functions.

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10.1209/epl/i1999-00217-9