Strongly charged flexible polyelectrolytes in poor solvents—from stable spheres to necklace chains

and

2000 EDP Sciences
, , Citation U. Micka and K. Kremer 2000 EPL 49 189 DOI 10.1209/epl/i2000-00133-6

0295-5075/49/2/189

Abstract

We present a first set of molecular dynamics (MD) simulations of solutions of strongly charged, salt-free polyelectrolyte chains in poor solvent with explicit counterions. As a function of concentration the regime from dominating electrostatic interaction to strong screening is covered. The conformations vary from strongly stretched rods to isolated, stable collapsed chains involving counterion condensation.

Export citation and abstract BibTeX RIS

10.1209/epl/i2000-00133-6