Abstract
We have investigated the growth of Ag(001) in the multilayer regime by high-resolution electron diffraction (SPA-LEED). Ag deposition at temperatures above 180 K results in the growth of approximately square mounds with a predominant ⟨10⟩ step termination which is thermodynamically favored. Surprisingly, when the deposition temperature is reduced below 130 K, instead of observing a random roughening of the step profile, as expected in a self-affine growth regime, the proliferation of ⟨001⟩ oriented facets is observed. We attribute our observation to the de-activation of corner crossing, as well as to the presence of easy pathways for interlayer diffusion down the {111} facets which are formed at ⟨10⟩ steps.
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