The measurement by SAXS of the nematic order parameter of laponite gels

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2002 EDP Sciences
, , Citation B. J. Lemaire et al 2002 EPL 59 55 DOI 10.1209/epl/i2002-00159-8

0295-5075/59/1/55

Abstract

We performed small-angle X-ray scattering (SAXS) experiments on oriented samples of laponite clay gels obtained by slow evaporation. The SAXS patterns are clearly anisotropic, which demonstrates the existence of nematic-like orientational correlations of the laponite disc-like particles. The iso-intensity lines of the SAXS patterns are elliptical and roughly homothetic over the whole scattering vector range examined in this experiment. The value of the nematic order parameter, , derived from the SAXS patterns is comparable to that of usual liquid crystals. This large value proves the importance of orientational correlations in these gels at concentrations higher than 0.02 g·cm−3, even in the absence of shear.

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10.1209/epl/i2002-00159-8