Percolation, depinning, and avalanches in capillary condensation of gases in disordered porous solids

, and

2003 EDP Sciences
, , Citation M. L. Rosinberg et al 2003 EPL 62 377 DOI 10.1209/epl/i2003-00407-y

0295-5075/62/3/377

Abstract

We propose a comprehensive theoretical description of hysteresis in capillary condensation of gases in mesoporous disordered materials. Applying mean-field density-functional theory to a coarse-grained lattice-gas model, we show that the morphology of the hysteresis loops is influenced by out-of-equilibrium transitions that are different on filling and on draining. In particular, desorption may be associated to a depinning process and be percolation-like even without explicitly introducing pore-blocking effects.

Export citation and abstract BibTeX RIS

10.1209/epl/i2003-00407-y