Interactions between polyelectrolyte-macroion complexes

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2003 EDP Sciences
, , Citation H. Boroudjerdi and R. R. Netz 2003 EPL 64 413 DOI 10.1209/epl/i2003-00218-2

0295-5075/64/3/413

Abstract

We consider structures formed by one semiflexible polyelectrolyte (PE) and one oppositely charged sphere and calculate the interaction between two such complexes within the ground-state approximation, where the PE assumes its optimal configuration. Using parameters appropriate for DNA-histone systems, we find the second virial coefficient of inter-complex interactions to be negative for intermediate salt concentrations within the range where stable complexes are formed, in agreement with experiments. A simple screened monopole-dipole model reproduces these findings.

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10.1209/epl/i2003-00218-2