Confinement effects on the excess wing in the dielectric loss of glass-formers

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2003 EDP Sciences
, , Citation R. Bergman et al 2003 EPL 64 675 DOI 10.1209/epl/i2003-00615-y

0295-5075/64/5/675

Abstract

We present results from dielectric spectroscopy on four molecular glass-formers, both in bulk and in confined geometry. For systems exhibiting a well-resolved secondary (β) relaxation, the confinement induces a relative enhancement (compared to the main α relaxation) of the effective dielectric strength of the β process. In bulk systems without a well-separated β process a similar relative enhancement is found also for the contribution to the dielectric loss identified as the excess wing. The latter effect results in a bimodal loss, which suggests that the excess wing should be attributed to a relaxation process separate from, and thus not a feature of, the α relaxation. The results hence provide an explanation for the much debated excess wing often observed in the dielectric response of glass-formers.

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10.1209/epl/i2003-00615-y