Direct observation of the crossover from α-relaxation to Rouse dynamics in a polymer melt

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2004 EDP Sciences
, , Citation D. Richter et al 2004 EPL 66 239 DOI 10.1209/epl/i2003-10180-5

0295-5075/66/2/239

Abstract

In this letter we report a large experimental effort exploring the dynamics of poly(vinyl ethylene) on length scales covering Rouse dynamics and below. The results establish the simultaneous existence of a generic sublinear diffusion regime which underlies the α-process in addition to the Rouse process. Both regimes are separated by a well-defined dynamic crossover. From that the size of the Gaussian blobs making up the Rouse model is determined directly. Following this observation, we may identify the universal glassy dynamics with subdiffusive motions occurring within these Gaussian blobs.

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10.1209/epl/i2003-10180-5