Equilibrium onions?

, , and

2004 EDP Sciences
, , Citation L. Ramos et al 2004 EPL 66 888 DOI 10.1209/epl/i2003-10260-6

0295-5075/66/6/888

Abstract

We demonstrate the possibility of a stable equilibrium multi-lamellar ("onion") phase in pure lamellar systems (no excess solvent) due to a sufficiently negative Gaussian curvature modulus. The onion phase is stabilized by non-linear elastic moduli coupled to a polydisperse size distribution (Apollonian packing) to allow space-filling without appreciable elastic distortion. This model is compared to experiments on copolymer-decorated lamellar surfactant systems, with reasonable qualitative agreement.

Export citation and abstract BibTeX RIS

10.1209/epl/i2003-10260-6