Measurement of the coalescence frequency in surfactant-stabilized concentrated emulsions

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2004 EDP Sciences
, , Citation V. Schmitt and F. Leal-Calderon 2004 EPL 67 662 DOI 10.1209/epl/i2004-10100-3

0295-5075/67/4/662

Abstract

We produce different oil-in-water concentrated emulsions stabilized by surfactants and we follow their kinetic evolution. We get evidence that the size evolution is first determined by Ostwald ripening and then by coalescence. The crossover between the two regimes occurs at a well-defined droplet diameter that characterizes the surfactant monolayer. We exploit this general type of evolution to measure the characteristic coalescence frequency in the thin liquid films.

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