Sliding friction between an elastomer network and a grafted polymer layer: The role of cooperative effects

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Published 23 February 2005 2005 EDP Sciences
, , Citation T. Vilmin and E. Raphael 2005 EPL 69 971 DOI 10.1209/epl/i2004-10451-7

0295-5075/69/6/971

Abstract

We study the friction between a flat solid surface where polymer chains have been end-grafted and a cross-linked elastomer at low sliding velocity. The contribution of isolated grafted chains' penetration in the sliding elastomer has been early identified as a weakly velocity-dependent pull-out force. Recent experiments have shown that the interactions between the grafted chains at high grafting density modify the friction force by grafted chain. We develop here a simple model that takes into account those interactions and gives a limit grafting density σl beyond which the friction no longer increases with the grafting density, in good agreement with the experimental data.

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10.1209/epl/i2004-10451-7