Origin of slow relaxation in liquid-water dynamics: A possible scenario for the presence of bottleneck in phase space

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Published 10 February 2006 2006 EDP Sciences
, , Citation A. Shudo et al 2006 EPL 73 826 DOI 10.1209/epl/i2005-10483-5

0295-5075/73/6/826

Abstract

We study slow relaxation in dynamics of liquid water at room temperatures and propose a consistent interpretation explaining why liquid-water dynamics exhibits power law relaxation behavior and can form the bottleneck in phase space even though it is a many-dimensional and strongly chaotic system. Our idea is inspired by recent developments of perturbation theories of Hamiltonian systems, and is reminiscent of the so-called Boltzmann-Jeans conjecture. Within this scenario, it is natural to expect that slow relaxation is not limited to liquid-water dynamics. We found that our hypothesis works well in predicting the relaxation properties of other molecules. The relation to the potential landscape picture is also discussed.

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10.1209/epl/i2005-10483-5