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Electron transfer in donor-acceptor systems: Many-particle effects and influence of electronic correlations

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Published 10 February 2006 2006 EDP Sciences
, , Citation S. Tornow et al 2006 EPL 73 913 DOI 10.1209/epl/i2005-10479-1

0295-5075/73/6/913

Abstract

We investigate electron transfer processes in donor-acceptor systems with a coupling of the electronic degrees of freedom to a common bosonic bath. The model allows to study many-particle effects and the influence of the local Coulomb interaction U between electrons on donor and acceptor sites. Using the non-perturbative numerical renormalization group approach we find distinct differences between the electron transfer characteristics in the single- and two-particle subspaces. We calculate the critical electron-boson coupling αc as a function of U and show results for density-density correlation functions in the whole parameter space. The possibility of many-particle (bipolaronic) and Coulomb-assisted transfer is discussed.

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10.1209/epl/i2005-10479-1