Hard colloidal rods near a soft wall: Wetting, drying, and symmetry breaking

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Published 17 May 2006 2006 EDP Sciences
, , Citation K. Shundyak and R. van Roij 2006 EPL 74 1039 DOI 10.1209/epl/i2006-10062-4

0295-5075/74/6/1039

Abstract

Within an Onsager-like density functional theory we explore the thermodynamic and structural properties of an isotropic and nematic fluid of hard needle-like colloids in contact with a hard substrate coated with a soft short-ranged attractive or repulsive layer. As a function of the range and the strength of the soft interactions we find wetting and drying transitions, a pre-drying line, and a symmetry-breaking transition from uniaxial to biaxial in the wetting and drying film.

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10.1209/epl/i2006-10062-4