Phase transitions in block copolymers resulting in a discontinuous change of the spatial period of mesophases

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Published 8 November 2006 2006 EDP Sciences
, , Citation S. Kuchanov et al 2006 EPL 76 959 DOI 10.1209/epl/i2006-10363-6

0295-5075/76/5/959

Abstract

The phase behavior of a melt of two-scale multiblock copolymers has been theoretically studied in the framework of the Weak Segregation Limit theory with a two-component order parameter. The existence of a thermodynamically stable mesophase with two scales of the space periodicity has been revealed for a melt of monodisperse nonperiodic heteropolymers. For the first time a discontinuous change with temperature of the spatial period of the mesophases has been predicted.

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10.1209/epl/i2006-10363-6