Properties of wave packets deduced from quantum control fitness landscapes

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Published 24 October 2007 Europhysics Letters Association
, , Citation P. Marquetand et al 2007 EPL 80 53001 DOI 10.1209/0295-5075/80/53001

0295-5075/80/5/53001

Abstract

We demonstrate the versatility of shaped femtosecond dump pulses for the investigation of molecular quantum systems. Model calculations show that population is most efficiently transferred by shaped pulses. Illustrative fitness landscapes, where the excited-state population is analyzed as a function of selected laser pulse parameters, facilitate a characterization of wave packet evolution and the potential energy surfaces. A first experimental implementation is presented for retinal photoisomerization in bacteriorhodopsin.

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10.1209/0295-5075/80/53001