Nonlinear diffusion from Einstein's master equation

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Published 13 November 2007 Europhysics Letters Association
, , Citation J. P. Boon and J. F. Lutsko 2007 EPL 80 60006 DOI 10.1209/0295-5075/80/60006

0295-5075/80/6/60006

Abstract

We generalize Einstein's master equation for random-walk processes by considering that the probability for a particle at position r to make a jump of length j lattice sites, Pj(r), is a functional of the particle distribution function f(r, t). By multiscale expansion, we obtain a generalized advection-diffusion equation. We show that the power law Pj(r)∝f(r)α-1 (with α>1) follows from the requirement that the generalized equation admits scaling solutions (f(r;t)=t−γϕ(r/tγ)). The solutions have a q-exponential form and are found to be in agreement with the results of Monte Carlo simulations, so providing a microscopic basis validating the nonlinear diffusion equation. Although its hydrodynamic limit is equivalent to the phenomenological porous media equation, there are extra terms which, in general, cannot be neglected as evidenced by the Monte Carlo computations.

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10.1209/0295-5075/80/60006