Modelling chemical reactions using semiconductor quantum dots

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Published 13 November 2007 Europhysics Letters Association
, , Citation A. Yu. Smirnov et al 2007 EPL 80 67008 DOI 10.1209/0295-5075/80/67008

0295-5075/80/6/67008

Abstract

We propose the use of semiconductor quantum dots for simulating chemical reactions, as electrons are redistributed among such artificial atoms. We show that it is possible to achieve various reaction regimes and obtain different reaction products by varying the speed of voltage changes applied to the gates forming quantum dots. Considering the simplest possible reaction, H2+H→H+H2, we show how the necessary initial state can be obtained and what voltage pulses should be applied to achieve a desirable final product. Our calculations have been performed using the Pechukas gas approach, which can be extended for more complicated reactions.

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10.1209/0295-5075/80/67008