Abstract
The ground state of a two-dimensional ionic mixture at zero pressure composed of oppositely charged spheres is determined as a function of the size asymmetry by using a penalty method. The cascade of stable structures includes square, triangular and rhombic crystals as well as "empty" crystals made up of dipoles and chains, which have a vanishing number density. Thereby we confirm the square structure, found experimentally on charged granulates, and predict new phases detectable in experiments on granular and colloidal matter.