The quantum-electrodynamic binding energiesB are
determined perturbatively to order (nα)2 for single
macroscopic bodies (quasi-continua mimicking atomic solids)
having the dispersive dielectric function ε(ω)≃{1 + 4πnαΩ2/(Ω2-(ω2-i0)2}, as if each atom were an oscillator of
frequency Ω, and n the number density of atoms
(pairwise separations ρ). The familiar divergences all
persist although they are modified by dispersion (finite
rather than infinite Ω); they must be controlled instead
by imposing the condition ρ>λ~(minimum lattice
spacing) <<c/Ω. QED gives identically the same
B = -(nα)2(1/2)∫λ∞dρ ρ2f(ρ)g(ρ) as one obtains from the properly retarded
attraction -α2f(ρ) between atoms, with g(ρ) a
correlation function defined purely by the geometry of the body.
The first three terms of the Taylor series for g are
determined, respectively, by volume V, surface area S and
any sharp edges. To order (nα)2, but not beyond, the
results for solid bodies lead directly to those for cavities of
the same shape and size in otherwise unbounded material.
Unlike the attraction between disjoint bodies, B for any
single finite body (typical linear dimensions a>>c/Ω)
is dominated by components proportional, respectively, to
(nα)2ℏΩ×{-V/λ3, + S/λ2, -a/λ (if there are edges) and ±log (c/2Ωλ)}. These always tend to induce collapse
rather than expansion. The pure Casimir components are of
order (nα)2ℏc/a, and (like the logarithmic terms) sometimes
positive, which makes them impossible to understand if the dominant
terms are disregarded. The B are found in closed form for
spheres, spherical shells and cubes, up to corrections
vanishing with λ. For unit length of an infinitely long
right circular cylinder of radius a, the standard V- and
S-proportional terms are corrected only by -(nα)2(π2ℏΩ/128a)log (c/2Ωλ); the pure
Casimir component, which would be proportional to (nα)2ℏc/a2,
vanishes through apparently accidental cancellations peculiar to
order (nα)2.