By applying the selection rules of auto-ionization to the (1s2s2p)4P state of the negative helium ion, it is shown that only the 4P5/2 energy level is not liable to auto-ionization. Provided the lowest triplet state of the atom has positive electron affinity, this ionic state is metastable in the same sense as the triplet state.
A thorough energy calculation of the quartet state of the ion has been carried through, and a positive electron affinity of at least 0.075 eV is found, enough to explain the experimental observation of it in the mass spectrograph as reported by Hiby. The unexplained line 310 061 cm-1 (322.5 Å) observed in the vacuum ultra-violet by Kruger may then probably correspond to the transition (2s2p2) 4P-(1s2s2p) 4P in He-, yielding an error of only 0.083 eV in the energy calculations.