Sintering occurs when powders are heated to temperatures near their melting points. This paper deals with the rapid increase of density during the sintering of single substances The increase of density cannot be explained by volume diffusion of vacant lattice sites or surface migration of atoms, but must involve macroscopic flow. The driving force for this flow is surface tension, and an equation connecting the rate of shear strain with the shear stress defines the resistance to deformation.
The density of a compact is calculated as a function of the time for two different laws of deformation, (a) that for a solid with a Newtonian viscosity, and (b) that for a Bingham solid which has a yield point and a rate of shear strain proportional to the difference between the applied shear stress and a yield stress. The effect of gas in the pores is calculated in the case of the viscous law.
The theory assumes that the pores are equal spheres and predicts that densification is uniform throughout a compact, independently of its shape and size, and suggests that gas pressures of a few atmospheres applied to the outside of a compact may appreciably increase the rate of sintering.
Relevant experiments and previous theories are examined critically, and it is shown that while the viscous model may explain the sintering of glasses it cannot explain that of metals. However, the experimental data can be explained by a model showing a yield point: on such a model the interaction of one pore with its neighbours is vital, so that pores in powder compacts close and isolated pores do not.