When, in cold-cathode discharge tubes, electrode spacings and surface areas deviate from the ideal of infinite parallel planes, it is found that the breakdown voltage between electrodes increases. This is explained as a decrease in the effective η of the gas due to loss of electrons and positive ions by diffusion to the walls of the container The loss factor per unit potential difference is shown theoretically to be inversely proportional to the field strength and tube radius, although this is not fully verified by experiment
Paschen curves obtained experimentally for potassium and nickel cathodes in argon and in a neon-argon mixture at low pressures are shown and, from these, values of γ for the two cathode surfaces are obtained as a function of E/p0. The apparatus used for measuring breakdown voltage is described.
Earlier theories of statistical and formative time delays are extended to cover the case of a rising overvoltage and also the case where the primary electrons appear in bursts as with ionization by α-particles. The shape of the statistical distribution curve is an indication of whether the primary electrons have been produced singly or in bursts. The overvoltage ΔV of breakdown due to formative lag and the rate of rise of the uniformly increasing applied voltage V are found to bear the relation ΔV ∝ (dV/dt)1/2. This has been experimentally verified.