The emission spectrum of SiF has been examined in the Schumann and infra-red regions. The system B-A (ν0, 0 = 11850.8 cm-1) is strong, and rotational analysis shows that both states are 2Σ. A new rotational analysis of the 0, 0 band of the α-system, A-X2π, although in substantial agreement with earlier work, confirms the view that state A is 2Σ+, and not 2π (case-b), as has previously been supposed. Violet degraded bands which have tentatively been ascribed to five systems, all with X2π as the ground state, are found, partly superimposed, in the region 51 000 to 53 500 cm-1. Three of the excited states of SiF appear to form a Rydberg series of 2Σ+ states leading to the ground state... π4σ2, 1Σ+ of SiF+. The ionization potential is found to be 7.28 eV. Evidence about the dissociation energy is briefly considered; the best value seems to be D0double prime(SiF) similar 125 kcal.