The validity of the nearly-free electron (`weak-binding') approximation is considered, for the problem of a single electron in a one-dimensional chain of potential wells lacking long-range order (a `liquid' chain), over an energy range forbidden for a periodic chain of the same mean spacing.
Central limit theorems for sums of dependent variates are used to obtain the probability distribution of the Fourier components of the potential. It is shown that the findings justify a definite evaluation of the potential `power spectrum'.
A second-order expression for the energy, in weak-binding approximation, is then evaluated. The implied eigenstate density is compared with the results of Monte Carlo calculations for chains of δ-function wells. The comparison shows the fit to be good for large disorders, but very poor for small disorders.
The findings are explained in the light of knowledge regarding localized states in this energy region. The trial wave function used in the weak-binding approach can approximate to a localized state, but only for disorders large enough to destroy the gap. The relevance of this finding to work with real liquids is discussed.