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TOPICAL REVIEW

Colloidal gels: equilibrium and non-equilibrium routes

Published 17 July 2007 IOP Publishing Ltd
, , Citation Emanuela Zaccarelli 2007 J. Phys.: Condens. Matter 19 323101 DOI 10.1088/0953-8984/19/32/323101

0953-8984/19/32/323101

Abstract

We attempt a classification of different colloidal gels based on colloid–colloid interactions. We discriminate primarily between non-equilibrium and equilibrium routes to gelation, the former case being slaved to thermodynamic phase separation while the latter is individuated in the framework of competing interactions and of patchy colloids. Emphasis is put on recent numerical simulations of colloidal gelation and their connection to experiments. Finally, we underline typical signatures of different gel types, to be looked at, in more detail, in experiments.

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