The impact of the CPT-Odd electroweak gauge sector of the Standard Model Extension on the electromagnetic properties of charged leptons is studied. This gauge sector is characterized by the
and
Lorentz violation (LV) coefficients, which have positive mass dimension because they are associated with a UY(1)-invariant and with an SUL(2)-invariant dimension-three operators, respectively. They belong to the category of relevant interactions, which can have strong effects on low-energy observables. We present a comprehensive study on the impact of this sector on the magnetic dipole moment (MDM) and the electric dipole moment (EDM) of charged leptons, up to second order in these LV coefficients, both at the tree and one-loop levels. We find that the O(ki) contributions at the tree and one-loop levels depend on energy, while
ones at the tree-level do not. As for
one-loop effects, there are both energy-dependent and energy-independent contributions, but we have focused only on those of the latter type. We find that the EDM only is generated at O(ki) up to one-loop level, whereas the MDM receives contributions from both O(ki) and
at both tree and one-loop levels. The contributions of O(ki) to the MDM are found to be suppressed relative to the corresponding contributions to the EDM by approximately three orders of magnitude. Using a recent experimental limit on the electron EDM the
bound was obtained. As far as the contributions of
are concerned, we find that the tree-level contributions are suppressed with respect to the one-loop ones by at least a factor of
. We find that the contribution to the electron MDM is by far the dominant one, as it can be up to four and seven orders of magnitude greater than those of the muon and tau, respectively. The Lorentz coefficient
of the Carroll–Field–Jackiw's QED is given by a linear combination of the
and
vectors. Assuming that
and taking
, which implies that
and
are collinear, we obtain an upper bound of
. The fact that
is an observer Lorentz invariant allows us to introduce a new-physics scale through
, for which we obtain the upper limit ΛCPT < 2.08 × 10−5me. The physical implications derived from the fact that the LV coefficients have positive mass units are discussed.