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Optical characterization of hierarchical ZnO structures grown with a simplified vapour transport method

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Published 1 May 2007 IOP Publishing Ltd
, , Citation V V Ursaki et al 2007 Nanotechnology 18 215705 DOI 10.1088/0957-4484/18/21/215705

0957-4484/18/21/215705

Abstract

A new ZnO micro/nanostructure morphology in the form of micro-torches was grown in the family of ZnO hierarchical structures by a simplified thermal chemical vapour transport and condensation method using a vertical furnace. It is formed by two basic parts: a three-dimensional (3D) crystal base and one-dimensional (1D) nanorods nucleated from this base. Mechanisms of this micro/nanostructure growth are suggested to be governed by the change of the ZnO vapour supersaturation level during the crystal growth. Micro-Raman analysis demonstrates good crystal lattice quality, independent of the micro/nanostructure morphology. Differences in the luminescence characteristics inherent to the different parts of the micro/nanostructure are expected to be useful for the development of micro/nano-optoelectronic devices.

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10.1088/0957-4484/18/21/215705