Ferroelectric ceramic samples of PbTiO3,
prepared by a modified oxide-mixing technique, were examined by x-ray
diffraction (XRD) and transmission electron microscopy (TEM) techniques for
crystalline and microstructural characterization. XRD clearly revealed only a
monophasic perovskite of tetragonal symmetry for the reference PbTiO3,
which was established to possess both a–a-and a–c-type
90°
domains. The inclination was approximately 2°
between the two different domains, as observed by high-resolution TEM.
Inductively coupled plasma (ICP) analysis, electron probe microanalysis (EPMA),
and x-ray photoelectron spectroscopy (XPS) were employed and the ensuing
chemical composition results are discussed. The approximate molar ratios of
Pb:Ti were 1:1, 1:1.5, and 1:0.8 as obtained by ICP analysis, EPMA, and
XPS, respectively. Corrections for the sensitivity factor (SCorr)
for Pb 4f, Ti 2p and the substitution of the matrix factors for FTi,Pb, FPb,Ti
have been taken into account in obtaining the Pb:Ti ratio of
1:1 by XPS quantification. The sensitivity factor (SKratos)
given by the instrumental maker was compared with the theoretical one (STheo)
and the result is also discussed.