When both intermolecular dipolar couplings (D couplings) and intramolecular
scalar couplings (J couplings) exist in a highly polarized multiple-spin
liquid, some forbidden nuclear magnetic resonance signals originating from intermolecular
multiple-quantum coherences may become observable. Moreover, their multiplet
patterns are quite different from what are observed in a multiple-spin
system with J couplings only. In this paper, these forbidden resonance peaks
and unique multiplet patterns are studied theoretically and experimentally.
For comparison and verification, an I2S3+X spin system is chosen as an
example to present five types of signal patterns from the interactions ofD and J couplings with either selective or non-selective
radio-frequency pulse sequences
for double-quantum coherences. The multiplet pattern rules for a more
general IpSq+Xk (p,q,k = 1,2,3,...) spin system
are derived as
well. It is demonstrated that some unusual multiplet amplitude patterns such
as (1:0:–1) may ``magnify'' J splittings, allowing more accurate measurement
of J coupling in the case of small J coupling constants and/or in inhomogeneous
fields. It is shown that the theoretical predictions, computer
simulations and experimental observations are all in agreement with one another
very well.