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Entropy production as correlation between system and reservoir

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Published 15 January 2010 Published under licence by IOP Publishing Ltd
, , Citation Massimiliano Esposito et al 2010 New J. Phys. 12 013013 DOI 10.1088/1367-2630/12/1/013013

1367-2630/12/1/013013

Abstract

We derive an exact (classical and quantum) expression for the entropy production of a finite system placed in contact with one or several finite reservoirs, each of which is initially described by a canonical equilibrium distribution. Although the total entropy of system plus reservoirs is conserved, we show that system entropy production is always positive and is a direct measure of system–reservoir correlations and/or entanglements. Using an exactly solvable quantum model, we illustrate our novel interpretation of the Second Law in a microscopically reversible finite-size setting, with strong coupling between the system and the reservoirs. With this model, we also explicitly show the approach of our exact formulation to the standard description of irreversibility in the limit of a large reservoir.

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