Nanoscience is certain to play a crucial role within many areas of technological development over the coming years. It is therefore necessary, at the beginning of the new century, to adapt to this extremely important subject. Due to the highly interdisciplinary nature of the field, comprising of features from different parts of physics (solid state, magnetism, quantum mechanics, optics, thermodynamics, surface physics, etc), chemistry, electronic engineering, and, so far to a lower extent, also biology, it is necessary to create a discussion platform which encompasses some of its facets.
A vast range of experimental and theoretical work has shown that isolated metal clusters possess many interesting features which differ distinctly from what is known, from both surface/solid state physics and atomic and molecular physics. For example, metal (as well as semiconductor or carbon) clusters exhibit electronic level structures which often change completely when the number of atoms in the cluster, N, changes by just one unit. Correspondingly the work functions are very sensitive to N, as are the chemical reactivities. Similar strong N-dependencies have been found in the optical absorption and the magnetism of clusters.
To realise possible technical applications of these new properties, a prerequisite is to bring the cluster into an environment, such as an encapsulating matrix or a surface. Due to the interaction with the contact medium, the properties of the clusters might change or even disappear. Additionally, with increasing coverage or volume filling, electronic and/or magnetic coupling will lead to a change of the functionality and enable a fine-tuning of the behaviour of the new devices. The physics of the cluster-on-surface system is therefore of fundamental importance.
Investigative efforts must focus on both the surface and the cluster science. In the past the two communities have more or less been separated although, despite this, there are similarities in some of the theoretical and experimental methods employed. The aim of this Focus Issue is therefore to fuel the discussion between these two fields in order to answer questions related to the interaction of clusters with surfaces. Accordingly, topics including atom diffusion, aggregation, self-organisation, and electronic and optical properties, as well as questions of possible applications (e.g. catalysis) are addressed.
The rapid development within the fields of cluster and nanoparticle physics clearly indicates the vital role that will be played by these systems in the future. At this point, however, it is clear that the area of nanostructure physics is expanding in a number of different directions, each requiring specific attention. There is a community working on large particles, i.e. on systems with several thousands of atoms where the exact number of atoms plays a minor role (e.g., in catalysis or magnetism). Other groups concentrate on clusters and nanostructures that are in the size range where each atom counts. This means that the physical and chemical properties might change dramatically as a function of the size or even the geometrical structure of a system.
While it is necessary to further investigate the new physics of nanoparticles, particular effort must also be placed on studying the functionality of clusters in appropriate environments. For example, nanomagnetism is a highly demanding fundamental problem as well as being important for future storage devices - in order to increase the writing density of recording media the magnetic domains have to be reduced in size. Ultimately the question must be answered as to which minimum size a technically usable magnetic domain can be reduced. Despite not yet having a complete picture of nanomagnetism, it is possible to observe (e.g., enhanced magnetic moments in small clusters), and to record hysteresis curves of single nanoparticles. The example of nanomagnetism clearly shows the strong interrelation between electronic and structural properties and functionality.
Focus on Clusters at Surfaces Contents
Al2O3-films on
Ni3Al(111):
a template for nanostructured cluster growthC Becker, A Rosenhahn, A Wiltner, K von
Bergmann, J Schneider, P Pervan,
M Milun, M Kralj and K Wandelt
Quantum-dot systems prepared by 2D organization of
nanoclusters preformed in the gas phase on functionalized
substratesA Perez, L Bardotti, B Prevel,
P Jensen, M Treilleux, P Mélinon,
J Gierak, G Faini and D Mailly
Synthesis and magnetic
properties of nanoscale bimetallic
Co1Rh1 particlesD Zitoun, C Amiens,
B Chaudret, M Respaud, M-C Fromen,
P Lecante and M-J Casanove
Stabilization of
Si-based cage clusters and nanotubes by encapsulation of
transition metal atomsAntonis N Andriotis, Giannis Mpourmpakis,
George E Froudakis and Madhu Menon
Magnetic
behaviour of thin films produced by depositing pre-formed Fe and
Co nanoclustersC Binns and M J Maher
Organization and magnetic properties of
cigar-shaped ferrite nanocrystalsA T Ngo and M P Pileni
Subsequent layer growth of supported
nanoparticles by deposition of Sb4 clusters onto
MoS2(0001)B Stegemann, B Kaiser and K Rademann
Plasmon
resonances in large noble-metal clustersC Sönnichsen, T Franzl, T Wilk, G von
Plessen and J Feldmann
Transient electron energy distribution in
supported Ag nanoparticlesM Merschdorf, C Kennerknecht, K Willig and W Pfeiffer
Spin and orbital magnetic moments of deposited
small iron clusters studied by x-ray magnetic circular dichroism
spectroscopyJ T Lau, A Föhlisch, M Martins, R Nietubyc, M Reif and W Wurth
Spin moments,
orbital moments and magnetic anisotropy of finite-length Co
wires deposited on Pd(110)R Félix-Medina, J Dorantes-Dávila and
G M Pastor
Thermal emission of electrons from
highly excited Na16+ to Na250+M Maier, M Astruc Hoffmann and B von Issendorff
Surface-induced reactions and
dissociations of small acetone, acetonitrile and ethanol
cluster ions: competitive chemical reactions, dissociation
mechanisms and determination of dissociation energyC Mair, J Fedor , M Lezius,
P Scheier, M Probst, Z Herman and
T D Märk
Nanostructuration with visible-light-emitting silicon nanocrystalsF Huisken, D Amans, G Ledoux, H Hofmeister, F Cichos and J Martin
Nonequilibrium electron energy-loss kinetics in metal
clustersC Guillon, P Langot, N Del Fatti and F Vallée
A study of charge quantization on
ligand-stabilized Au5 cluster monolayersH Zhang, D Mautes and U Hartmann
Large noble metal clusters: electron
confinement and band structure effectsH Hövel and I Barke
Temperature dependence of the
magnetization in Fe islands on W(110): evidence for
spin-wave quantizationV Senz, R Röhlsberger, J Bansmann, O Leupold and
K-H Meiwes-Broer
Karl-Heinz Meiwes-Broer, Universität Rostock, Germany
Wilfried Wurth, Universität Hamburg, Germany
Hans-Peter Steinrück, Universität Erlangen-Nürnberg, Germany