The Paper gives an account of preliminary investigations into the spreading of liquids on mercury. Water and solutions of a number of inorganic substances are tested.
Purest "conductivity" water in the presence of air is found to spread very slowly on a clean mercury surface; the spreading is greatly accelerated by traces of acid in solution, and totally inhibited by traces of alkali.
All the neutral salts tested, even chlorides of mercury and silver, are found to produce rapid spreading. By varying the concentration of the solution the rate of spreading is controlled; the phenomena are described and photographed.
All acid solutions tested spread rapidly, probably reacting chemically with the mercury. One part of hydrochloric acid in ten million of water definitely accelerates spreading. A drop of very dilute acid spreads rapidly to cover a definite area and stops, any further spreading being as slow as that of water. The area covered during the rapid stage depends on the nature of the acid; it is proportional to the number of acid molecules present, and is larger than would be expected if a monomolecular layer of the appropriate salt were formed on the mercury surface.
Drops of certain alkaline solutions, notably ammonia, are found to spread after a period of delay, the spreading being due to carbon dioxide absorbed from the air.
Electrostatic fields up to 4,000 volts/cm. applied perpendicular to the surface produce no visible results. Placing a platinum wire from one terminal of a battery in the mercury and from the other terminal in the drop, and applying small voltages, causes spreading even in alkalis if the mercury be positive, and prevents spreading even in dilute acids if the mercury be negative.
Increasing the field beyond that necessary to prevent spreading (mercury negative) sets up an oscillation, the drop spreading till it breaks contact with the terminal, and then contracting. An E.M.F. of 400 volts was required to produce this effect with a drop of conductivity water.
A method of photographing films on the surface of mercury is described. By the same means a photograph is obtained showing a drop of oil spreading on a water surface. The spreading film is preceded by a well defined ridge, probably that observed by Osborne Reynolds, but apparently by none of the more recent writers.
The Paper concludes with a description of a ridge that may be observed under certain conditions when water is draining from a sheet of perfectly clean glass.