Paper • The following article is Open access

An energy competition of Co3+ and Co4+ ions during spin state transition in Ca3Co4O9 complex

, and

Published under licence by IOP Publishing Ltd
, , Citation N Karaman et al 2016 J. Phys.: Conf. Ser. 667 012008 DOI 10.1088/1742-6596/667/1/012008

Download Article PDF

Article metrics

6537 Total downloads

Share this article

Author e-mails

nkaraman@adiyaman.edu.tr

Author affiliations

1 Adiyaman University, Science and Art Faculty, Physics Department, 02040, Adiyaman, Turkey

2 Inonu University, Science and Arts Faculty, Physics Department, 44280, Malatya, Turkey

3 Adiyaman University, Education Faculty, Science Education Department, 02040, Adiyaman, Turkey

Buy this article in print

Journal RSS
Sign up for new issue notifications
1742-6596/667/1/012008

Abstract

The magnetic behavior of Ca3Co4O9 complex shows a very interesting phase transition at high temperature. It is probably that this ordering is due to the spin states of Co3+ and Co4+ ions. It is quite obvious that spin states of Co ions generally change as a function of temperature. We have shown that there is a strong correlation between oxidation states and ligand field parameters during spin state transitions.

Export citation and abstract BibTeX RIS

Previous article in issue
Next article in issue

Content from this work may be used under the terms of the Creative Commons Attribution 3.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.

Please wait… references are loading.
10.1088/1742-6596/667/1/012008