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Thermal Dynamics of Xanthene Dye in Polymer Matrix Excited by Double Pulse Laser Radiation

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, , Citation Ilia Samusev et al 2018 J. Phys.: Conf. Ser. 961 012011 DOI 10.1088/1742-6596/961/1/012011

1742-6596/961/1/012011

Abstract

Double-pulse laser excitation of the eosin and silver nanoparticles embedded into polymer media is known to be a method of electronic-vibrational energy deactivation kinetic process information obtaining and polymer thermal dynamics investigation. We have studied the vibrational relaxation processes in dye molecules (eosin) and nanoparticles in polyvinyl alcohol after two time-shifted laser pulses with fast and delayed fluorescence kinetics study. In order to simulate thermal and photophysical processes caused by double photon excitation, we solved heat transfer and energy deactivation differential equations numerically. The simulation allowed us to obtain the value of heat conductivity coefficient of polymer matrix.

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10.1088/1742-6596/961/1/012011